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Chemical Bonding Basics

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Hydrogen Bond

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An intermolecular attraction between a hydrogen atom, which is bound to a highly electronegative atom, and another electronegative atom with a lone pair of electrons.

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Triple Bond

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A covalent bond where three pairs of electrons are shared between two atoms.

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Polar Covalent Bond

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A type of covalent bond where electrons are shared unequally between two atoms due to a difference in their electronegativities, resulting in a dipole.

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Metallic Bond

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A bond found in metals, where there is a sea of shared free-floating valence electrons around positively charged metal ions.

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Single Bond

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A covalent bond in which only one pair of electrons is shared between atoms.

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Dative or Coordinate Bond

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A covalent bond where both electrons in the shared pair come from the same atom.

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Covalent Bond

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A chemical bond where atoms share one or more pairs of valence electrons to achieve a full outer shell, resulting in molecules.

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Nonpolar Covalent Bond

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A covalent bond where electrons are shared equally between two atoms with similar electronegativities, resulting in no permanent dipole.

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Double Bond

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A covalent bond in which two pairs of electrons are shared between two atoms.

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Ionic Bond

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A type of chemical bond where one or more electrons are transferred from one atom to another, resulting in cations and anions which are held together by electrostatic forces.

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Pi Bond (π Bond)

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A covalent bond formed by the side-to-side overlap of two atomic orbitals that supplies the second or third bond in double and triple bonds, respectively.

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Dipole-Dipole Interaction

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An intermolecular force between two polar molecules, where positive end of one molecule attracts the negative end of another molecule.

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Chemical Bond

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An attraction between atoms or ions that enables the formation of chemical substances containing two or more atoms.

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Sigma Bond (σ Bond)

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A covalent bond formed by the direct overlap of two atomic orbitals along the inter-nuclear axis.

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London Dispersion Forces

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A weak intermolecular force arising from induced temporary dipoles in otherwise nonpolar molecules.

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