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Crystallography

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Unit Cell

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The smallest repeating unit in a crystal lattice that reflects the symmetry and structure of the entire crystal.

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Lattice Parameter

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The physical dimensions of unit cells in a crystal lattice, often described by the lengths of the cell edges (a, b, c) and the angles between them (α, β, γ).

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Bragg's Law

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A fundamental equation that relates the angles at which X-rays are diffracted by crystal planes, given by nλ=2dsinθn\lambda = 2d\sin\theta, where nn is an integer, λ\lambda is the wavelength, dd is the distance between crystal planes, and θ\theta is the diffraction angle.

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X-ray Crystallography

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A technique for determining the atomic and molecular structure of a crystal by diffracting X-ray beams off its crystalline planes.

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Miller Indices

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A notation system that describes the orientation of crystal planes in a lattice, using a set of three integers (hkl).

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Space Group

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Describes the symmetry of a crystal structure in three dimensions, considering translational and point symmetries. There are 230 unique space groups.

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Crystal System

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A classification scheme for crystals based on the symmetry properties of the lattice. There are seven systems: cubic, tetragonal, orthorhombic, hexagonal, trigonal, monoclinic, and triclinic.

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Reciprocal Lattice

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A construct used to describe the diffraction pattern of a crystal lattice, where each point represents the diffraction condition for a set of lattice planes.

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Symmetry Operation

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An operation that moves a crystal in such a way that it looks the same after the operation as it did before. Examples include rotation, reflection, inversion, and translation.

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Point Group

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The group of symmetry operations that leave at least one point unmoved, describes symmetry of the molecule regardless of translational motions.

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Fourier Transform

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A mathematical operation that transforms crystallographic data from real space to reciprocal space, and is essential in interpreting X-ray diffraction data.

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Powder Diffraction

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A method where a polycrystalline powder is used for diffraction analysis, producing a series of rings that are unique to the crystal structure of the material.

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Laue Method

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A method of X-ray diffraction that involves exposing a stationary crystal to a polychromatic beam of X-rays to produce a pattern of spots which can be analyzed for crystal orientation.

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Anisotropy

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The property of being directionally dependent, as opposed to isotropy, which means homogeneous in all directions, often reflected in the physical properties of crystals.

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Ewald Sphere

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A concept used in crystallography to represent the condition for diffraction and the reciprocal lattice. A sphere with a radius equal to the inverse of the wavelength of the incident beam.

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