Logo
Pattern

Discover published sets by community

Explore tens of thousands of sets crafted by our community.

Maxwell's Relations in Thermodynamics

8

Flashcards

0/8

Still learning
StarStarStarStar

Clausius-Clapeyron Equation

StarStarStarStar

This equation provides the relationship between the pressure and temperature at phase boundaries and is used to describe the slope of phase transition lines on a P-T diagram.

StarStarStarStar

Second Maxwell Relation

StarStarStarStar

The second Maxwell relation is obtained from the enthalpy differential and connects the specific heat at constant pressure to the expansion coefficient and temperature.

StarStarStarStar

Fourth Maxwell Relation

StarStarStarStar

The fourth Maxwell relation stems from the Gibbs free energy and connects temperature and pressure changes with respect to entropy and volume.

StarStarStarStar

Helmholtz Free Energy Differential Form

StarStarStarStar

This equation describes how the Helmholtz free energy changes with changes in temperature and volume, important for understanding work in closed systems at constant temperature.

StarStarStarStar

First Maxwell Relation

StarStarStarStar

The first Maxwell relation is derived from the internal energy differential and relates entropy and volume to temperature and pressure.

StarStarStarStar

Heat Capacity Relation at Constant Pressure and Volume

StarStarStarStar

This formula relates heat capacities at constant pressure (Cp) and at constant volume (Cv), highlighting their difference in terms of the gas constant and the volume expansion coefficient.

StarStarStarStar

Gibbs Free Energy Differential Form

StarStarStarStar

This differential form highlights the changes in Gibbs energy as a result of changes in temperature and pressure, being fundamental in understanding chemical reactions and phase changes.

StarStarStarStar

Third Maxwell Relation

StarStarStarStar

The third Maxwell relation comes from the Helmholtz free energy and relates temperature and volume with entropy and pressure.

Know
0
Still learning
Click to flip
Know
0
Logo

© Hypatia.Tech. 2024 All rights reserved.