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Phase Diagrams and Triple Point
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Phase Boundaries
Phase boundaries on a phase diagram indicate the conditions of pressure and temperature under which two phases of a substance are in equilibrium. These lines separate different phases on the diagram.
Triple Point
The triple point in a phase diagram represents the unique set of conditions (pressure and temperature) at which three phases of a substance (solid, liquid, and gas) can coexist in equilibrium.
Critical Point
The critical point marks the end of the liquid-gas boundary on the phase diagram. Beyond this point, the liquid and gas phases become indistinguishable, and the substance exists as a supercritical fluid.
Gibbs Phase Rule
The Gibbs Phase Rule, described by the equation , where is the degrees of freedom, is the number of components, and is the number of phases, helps determine the number of variables that can be changed independently without altering the number of phases present.
Solid-Liquid-Gas Regions
The areas on the phase diagram labeled as solid, liquid, or gas indicate the range of pressures and temperatures over which that phase is stable and exists as the only phase.
Slope of Solid-Liquid Boundary
The slope of the solid-liquid boundary on a phase diagram indicates whether the solid phase is more or less dense than the liquid phase. A positive slope means the solid is denser than the liquid, while a negative slope suggests the reverse.
Fusion Curve
The fusion curve represents the boundary on a phase diagram that separates solid and liquid phases. It shows how the melting point of a substance changes with pressure.
Eutectic Point
A eutectic point represents a fixed combination of temperature and pressure where a mixture of substances can coexist as solids and a liquid, resulting in the lowest melting point for the mixture.
Supercritical Fluid Region
On a phase diagram, the supercritical fluid region lies beyond the critical point. In this region, the substance doesn’t have distinct liquid or gas phases. Conditions here allow the supercritical fluid to exhibit unique properties.
Sublimation Curve
The sublimation curve on a phase diagram separates the solid and gas phases and indicates the conditions under which a substance can pass directly from the solid to the gas phase (sublimation) or vice versa.
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