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The Gibbs Free Energy
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Gibbs Free Energy and Phase Transitions
During a phase transition (e.g., solid to liquid), the Gibbs Free Energy of the phases in question are equal, as the system is at equilibrium and the transition occurs at a constant temperature and pressure.
Gibbs Free Energy Formula
The Gibbs Free Energy (G) is defined by the equation , where is the enthalpy, is the absolute temperature, and is the entropy.
Relationship Between Gibbs Free Energy and Work
Gibbs Free Energy is often used to calculate the maximum amount of non-expansion work that can be done in a thermodynamic process, such as electrical work in a galvanic cell.
Definition of Gibbs Free Energy
Gibbs Free Energy (G) is the thermodynamic potential that measures the maximum or reversible work that may be performed by a thermodynamic system at a constant temperature and pressure.
Equilibrium and Gibbs Free Energy
At equilibrium, the change in Gibbs Free Energy (ΔG) is zero, indicating that the system is at its lowest energy state for the given temperature and pressure conditions.
Gibbs Free Energy and Reaction Direction
The sign of ΔG determines the direction of the chemical reaction; if ΔG is positive, the reaction proceeds in the reverse direction.
Spontaneity and Gibbs Free Energy
A reaction is spontaneous if the Gibbs Free Energy change (ΔG) is negative (), meaning that the process can occur without being driven by an external force.
Standard Gibbs Free Energy Change
The standard Gibbs Free Energy change (ΔG°) is the change in Gibbs energy for a process where all reactants and products are in their standard states (usually 1 bar of pressure at the given temperature).
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