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The Gibbs Free Energy

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Gibbs Free Energy and Phase Transitions

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During a phase transition (e.g., solid to liquid), the Gibbs Free Energy of the phases in question are equal, as the system is at equilibrium and the transition occurs at a constant temperature and pressure.

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Gibbs Free Energy Formula

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The Gibbs Free Energy (G) is defined by the equation G=HTSG = H - TS, where HH is the enthalpy, TT is the absolute temperature, and SS is the entropy.

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Relationship Between Gibbs Free Energy and Work

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Gibbs Free Energy is often used to calculate the maximum amount of non-expansion work that can be done in a thermodynamic process, such as electrical work in a galvanic cell.

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Definition of Gibbs Free Energy

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Gibbs Free Energy (G) is the thermodynamic potential that measures the maximum or reversible work that may be performed by a thermodynamic system at a constant temperature and pressure.

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Equilibrium and Gibbs Free Energy

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At equilibrium, the change in Gibbs Free Energy (ΔG) is zero, indicating that the system is at its lowest energy state for the given temperature and pressure conditions.

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Gibbs Free Energy and Reaction Direction

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The sign of ΔG determines the direction of the chemical reaction; if ΔG is positive, the reaction proceeds in the reverse direction.

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Spontaneity and Gibbs Free Energy

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A reaction is spontaneous if the Gibbs Free Energy change (ΔG) is negative (ΔG<0ΔG < 0), meaning that the process can occur without being driven by an external force.

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Standard Gibbs Free Energy Change

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The standard Gibbs Free Energy change (ΔG°) is the change in Gibbs energy for a process where all reactants and products are in their standard states (usually 1 bar of pressure at the given temperature).

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