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Second Law of Thermodynamics
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The Kelvin-Planck Statement
It is impossible for any device that operates on a cycle to receive heat from a single reservoir and produce a net amount of work.
Perpetual Motion Machines of the Second Kind
The second law of thermodynamics rules out the possibility of machines that can operate perpetually and provide energy without an input, known as perpetual motion machines of the second kind.
Carnot Efficiency
Carnot efficiency describes the maximum possible efficiency of a heat engine operating between two heat reservoirs, determined by their temperatures.
Second Law of Thermodynamics - Entropy
In any closed system, the total entropy either increases or remains constant over time, never decreasing.
Refrigerators and Heat Pumps
Refrigerators and heat pumps require external work to transfer heat from a colder body to a hotter body, in accordance with the second law.
The Clausius Statement
It is impossible to construct a device that will operate in a cycle and produce no effect other than the transfer of heat from a cooler to a hotter body.
Thermodynamic Equilibrium
A system is in thermodynamic equilibrium when it is in thermal, mechanical, and chemical equilibrium, resulting in no net flow of energy or matter and no change in entropy.
Heat Engines
Heat engines operate by converting heat energy to work, and in the process, they cannot be 100% efficient due to the increase in entropy.
Spontaneous Processes
A spontaneous process in thermodynamics is one that occurs naturally and without external influence, leading to an increase in the entropy of the system and its surroundings.
Entropy and Probability
The concept of entropy is linked to the probability distribution of microstates; systems tend to progress towards more probable (higher entropy) states.
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